|
|Section1= |Section2= |Section3= |Section4= }} Thiocyanic acid is a chemical compound with the formula HSCN that exists as a mixture with the isomeric compound isothiocyanic acid (HNCS).〔Holleman, A. F.; Wiberg, E. ''Inorganic Chemistry'' Academic Press: San Diego, 2001. ISBN 0-12-352651-5.〕 It is the sulfur analog of cyanic acid (HOCN). It is a weak acid, bordering on strong, with a pKa of 1.1 at 20 °C and extrapolated to zero ionic strength.〔Martell, A. E.; Smith, R. M.; Motelaitis, R. J. ''NIST Database 46'' National Institute of Standards and Technology: Gaithersburg, MD, 2001.〕 HSCN is predicted to have a triple bond between carbon and nitrogen. It has been observed spectroscopically but has not been isolated as a pure substance. The salts and esters of thiocyanic acid are known as thiocyanates. The salts are composed of the thiocyanate ion (−SCN) and a suitable metal cation (e.g., potassium thiocyanate, KSCN). The esters of thiocyanic acid have the general structure R-SCN. ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Thiocyanic acid」の詳細全文を読む スポンサード リンク
|