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Thiocyanic acid
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Thiocyanic acid : ウィキペディア英語版
Thiocyanic acid

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Thiocyanic acid is a chemical compound with the formula HSCN that exists as a mixture with the isomeric compound isothiocyanic acid (HNCS).〔Holleman, A. F.; Wiberg, E. ''Inorganic Chemistry'' Academic Press: San Diego, 2001. ISBN 0-12-352651-5.〕 It is the sulfur analog of cyanic acid (HOCN).
It is a weak acid, bordering on strong, with a pKa of 1.1 at 20 °C and extrapolated to zero ionic strength.〔Martell, A. E.; Smith, R. M.; Motelaitis, R. J. ''NIST Database 46'' National Institute of Standards and Technology: Gaithersburg, MD, 2001.〕
HSCN is predicted to have a triple bond between carbon and nitrogen. It has been observed spectroscopically but has not been isolated as a pure substance.
The salts and esters of thiocyanic acid are known as thiocyanates. The salts are composed of the thiocyanate ion (SCN) and a suitable metal cation (e.g., potassium thiocyanate, KSCN). The esters of thiocyanic acid have the general structure R-SCN.
==References==


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